Surveillance video from the area outside the nightclub and in Rhode Island, along with DNA evidence and other records were used to connect Campbell to the kidnapping and rape, prosecutors said.
Campbell is the brother of Boston City Councilor Andrea Campbell.
"I am heartbroken, saddened and devastated by this news. I will continue to pray for the victim who had the courage to come forward and I want her to get all of the supports, services, and protections she is entitled to," Andrea Campbell said Thursday in a statement. "I will also pray for my brother. I'm trusting that the judicial process will ensure that justice is served."
At the time of his arrest, Alvin Campbell was free on his own personal recognizance in connection with a separate assault charge he’s facing. Authorities said he accused of assaulting two women outside a Boston nightclub last spring.